Solid-state diffusion in amorphous zirconolite
نویسندگان
چکیده
منابع مشابه
Solid-State Diffusion and NMR
Diffusion in solids, which requires the presence of crystal defects or disorder, has both microscopic and macroscopic aspects. Nuclear magnetic resonance techniques provide access to microscopic diffusion parameters like atomic jump rates and activation energies as well as to the tracer diffusion coefficient for macroscopic transport. Microscopic NMR methods include spin-lattice relaxation spec...
متن کاملSolid state solvation in amorphous organic thin films.
The photoluminescence (PL) of the red laser dye DCM2, doped into blended thin films of polystyrene (PS) and the polar small molecule camphoric anhydride (CA), redshifts as the CA concentration increases. The DCM2 PL peaks at 2.20 eV (lambda=563 nm) for pure PS films and shifts to 2.05 eV (lambda=605 nm) for films with 24.5% CA (by mass). The capacitively measured electronic permittivity also in...
متن کاملSolid State Crystallinity, Amorphous State, and Its Implications in the Pharmaceutical Process
Many drugs exist in crystalline solid form due to reasons of stability and ease of handling during the various stages of drug development. Crystalline solids can exist in the form of polymorphs, solvates or hydrates. Phase transitions such as polymorph inter-conversion, formation of hydrates, desolvation of solvates, and conversion of the crystalline to amorphous form may occur during various p...
متن کاملSelf-Diffusion in Amorphous Silicon.
The present Letter reports on self-diffusion in amorphous silicon. Experiments were done on ^{29}Si/^{nat}Si heterostructures using neutron reflectometry and secondary ion mass spectrometry. The diffusivities follow the Arrhenius law in the temperature range between 550 and 700 °C with an activation energy of (4.4±0.3) eV. In comparison with single crystalline silicon the diffusivities are tre...
متن کاملMicrostructural stability of the Kirkendall plane in solid-state diffusion.
In a diffusion-controlled interaction, the Kirkendall plane, as marked by inert particles placed at the original contact surface of a reaction couple, need not be unique. Multiple planes can develop, and sometimes the Kirkendall plane does not exist at all. A phenomenological approach is introduced to rationalize the Kirkendall-effect-mediated migration of macroscopic inclusions inside a diffus...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of Applied Physics
سال: 2014
ISSN: 0021-8979,1089-7550
DOI: 10.1063/1.4901326